Вплив фретинг - процесів на склад водно - спиртових сумішей
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Дата
2017
Автори
Ганзюк, А.Л.
Олександренко, В.П.
Нездоровін, В.П.
Hanzyuk, A.L.
Oleksandrenko, V.P.
Nesdorovin, V.P.
Назва журналу
Номер ISSN
Назва тому
Видавець
Хмельницький національний університет
Анотація
Проведено дослідження впливу фретинг-процесів у спиртових середовищах на мікрокомпонентний склад
спирту та структурних змін металевих поверхонь зразків із сталі 30ХГСА. Встановлено, що малоамплітудні циклічні
коливання ініціюють перебіг складних трибо - хімічних реакцій в результаті яких з більш простих за своєю будовою
органічних сполук утворюються більш складні та змінюється мікрокомпонентний склад спирту.
Conducted chromatographic study of the effect of fretting processes in alcohol environments on ScrollPoint the composition of alcohol. and structural changes of the metal surfaces of samples of steel 30ХГСA. Tribo-chemical reactions take place in the tribo-system, i.e. both in metal and in ethanol medium. The emission of electrons from the metal initiates the formation of free radicals in the alcohol solution, which then form more complex organic compounds. The ejection of electrons from metal surface to the environment leads to an increase in their concentration in the medium and initiates the flow of tribo-chemical reactions, which by their nature differ significantly from chemical. The erosion of the metal takes place by rupture of the metal ties under the action tribology fluctuations when there are variations of atoms with large amplitude. Found that low-amplitude cyclic fluctuations initiate the flow of complex tribo-chemical reactions which from the more simple structure of organic compounds formed more complex and changing ScrollPoint the composition of alcohol, namely increasing the number of ester – tamilanadu that has the most complex structural formula.
Conducted chromatographic study of the effect of fretting processes in alcohol environments on ScrollPoint the composition of alcohol. and structural changes of the metal surfaces of samples of steel 30ХГСA. Tribo-chemical reactions take place in the tribo-system, i.e. both in metal and in ethanol medium. The emission of electrons from the metal initiates the formation of free radicals in the alcohol solution, which then form more complex organic compounds. The ejection of electrons from metal surface to the environment leads to an increase in their concentration in the medium and initiates the flow of tribo-chemical reactions, which by their nature differ significantly from chemical. The erosion of the metal takes place by rupture of the metal ties under the action tribology fluctuations when there are variations of atoms with large amplitude. Found that low-amplitude cyclic fluctuations initiate the flow of complex tribo-chemical reactions which from the more simple structure of organic compounds formed more complex and changing ScrollPoint the composition of alcohol, namely increasing the number of ester – tamilanadu that has the most complex structural formula.
Опис
Ключові слова
фретинг - процес,, трибо - хімічні реакції, мікрокомпонентний склад спирту, framing-the process of tribo - chemical reaction, scrollpoint the composition of alcohol
Бібліографічний опис
Ганзюк, А.Л. Вплив фретинг - процесів на склад водно - спиртових сумішей [Текст] / А. Л. Ганзюк, В. П. Олександренко, В. П. Нездоровій // Проблеми трибології. – 2017. – №1. – С. 12-18.